easiest way would be to use a group member alert and specify the name of the group. Now if each member needs to go to a different person/group, then you'd be better off creating a node custom property called EmailContact, assigning that to the nodes, creating the needed values, then in a node down alert, or any node alert, use the variable ${EmailContact} in the To field and it will then pull the values for the specific node and send that way.
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